Material Safety Data Sheet
Cadmium Sulfate Anhydrous
ACC# 03800
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Section 1 - Chemical Product and Company Identification |
MSDS Name: Cadmium Sulfate Anhydrous
Catalog Numbers:
C23-100, C23-500
Synonyms:
Sulfuric acid cadmium salt
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 10124-36-4 |
Cadmium Sulfate |
100 | 233-331-6 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: white solid.
Danger! Toxic. Cancer hazard. Harmful if
swallowed. Causes eye and skin irritation. Contains cadmium. Avoid
creating dust. Causes digestive and respiratory tract irritation.
May cause blood abnormalities. May cause lung damage. May cause
liver and kidney damage.
Target Organs: Kidneys, liver, lungs, skeletal
structures.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause unconsciousness.
Inhalation:
Effects may be delayed. Causes respiratory tract irritation.
Irritation may lead to chemical pneumonitis and pulmonary edema. May
cause dyspnea (difficult or labored breathing). Damage may be
delayed. May cause anemia. May cause cough, chest pain, fever,
muscular cramps, and headache.
Chronic:
May cause respiratory tract cancer. Prolonged or repeated exposure
may cause permanent bone structure abnormalities. May cause liver and
kidney damage. May cause anemia and other blood cell abnormalities.
Chronic inhalation may cause pulmonary emphysema.
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Section 4 - First Aid Measures
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Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
The use of Calcium disodium EDTA as a chelating agent should be
determined by qualified medical personnel.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Substance
is noncombustible. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
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Section 7 - Handling and Storage
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Handling:
Wash hands before eating. Use with adequate ventilation. Avoid
contact with skin and eyes. Avoid ingestion and inhalation. Wash
clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Cadmium Sulfate
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0.01 mg/m3 TWA (as Cd); 0.002 mg/m3 TWA (respirable fraction, as Cd) (listed under Cadmium compounds).
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none listed
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2.5 æg/m3 Action Level (as Cd); 5 æg/m3 PEL (as Cd. Do not eat, drink or chew t obacco or gum or apply cosmetics in regulated areas. Carcinogen: dust can cause lung and kidney disease. See 29 CFR
1910.1027) (listed under Cadmium compounds).
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OSHA Vacated PELs:
Cadmium Sulfate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Solid
Appearance: white
Odor: odorless
pH: 3.5-6 (5% solution).
Vapor Pressure: Negligible.
Vapor Density: 7.2
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point:1832 deg F
Decomposition Temperature:Not available.
Solubility: 76% @ 0C in water.
Specific Gravity/Density:4.69
Molecular Formula:CdSO4
Molecular Weight:208.4676
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Violently reacts with magnesium and with aluminum powder when heated.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases, toxic cadmium
oxide fumes.
Hazardous Polymerization: Has not been reported.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 10124-36-4:
EV2700000
LD50/LC50:
CAS# 10124-36-4:
Oral, mouse: LD50
= 47 mg/kg;
Oral, rat: LD50 = 280
mg/kg;
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Carcinogenicity:
CAS# 10124-36-4:
- ACGIH:
A2 - Suspected Human Carcinogen (listed as 'Cadmium compounds').
- California:
carcinogen, initial date 10/1/87 (listed as Cadmium compounds).
- NTP:
Known carcinogen (listed as Cadmium compounds).
- IARC:
Group 1 carcinogen (listed as Cadmium compounds).
Epidemiology:
NIOSH cited recent epidemiological evidence of a
significant excess of respiratory cancer deaths among a
cohort of cadmium production workers, and concluded that
cadmium and its compounds are potential carcinogens.
Teratogenicity:
Experimental teratogenic effects have been reported.
Reproductive Effects:
Experimental reproductive effects have been reported.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
CADMIUM COMPOUNDS |
No information available. |
| Hazard Class: |
6.1 |
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| UN Number: |
UN2570 |
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| Packing Group: |
III |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 10124-36-4 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 10124-36-4: immediate, delayed.
Section 313
This material contains Cadmium
Sulfate (listed as Cadmium compounds), 100%, (CAS# 10124-36-4) which
is subject to the reporting requirements of Section 313 of SARA Title
III and 40 CFR Part 373.
Clean Air Act:
CAS# 10124-36-4 (listed as Cadmium compounds) is listed as a hazardous
air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
CAS# 10124-36-4 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 10124-36-4 can be found on the
following state right to know lists: California, (listed as Cadmium
compounds), New Jersey, Pennsylvania, Minnesota, (listed as Cadmium
compounds), Massachusetts.
California Prop 65
The following statement(s) is(are) made in order to comply with
the California Safe Drinking Water Act:
WARNING: This product contains Cadmium Sulfate, listed as `Cadmium
compounds', a chemical known to the state of California to cause
cancer.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T
Risk Phrases:
R 22 Harmful if swallowed.
R 49 May cause cancer by inhalation.
R 48/23/25 Toxic : danger of serious damage to health by prolonged
exposure through inhalation and if swallowed.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 53 Avoid exposure - obtain special instructions before use.
WGK (Water Danger/Protection)
CAS# 10124-36-4: 3
Canada - DSL/NDSL
CAS# 10124-36-4 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1A, D2A.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 10124-36-4 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 6/29/1998
Revision #3 Date: 2/10/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.